AbstractAromatic volatile organic compounds (VOCs) proved to have enhanced polluting behavior upon the atmosphere and human health. Their catalytic destruction is an alternative for environmental pollution reduction in the case of gaseous emissions with low contents of VOC.In this paper, an experimental study is presented, concerning the conversion of benzene and its mono-halogenated derivatives on SCR-DeNOx (V2O5-WO3/TiO2) commercial catalyst, specific for the reduction process of nitrogen oxid...
Autori: Florin Bandrabur, Heinz Koser, Ion Balasanian, Liliana Lazar
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25105

A series of new Ni(II) poly-phosphinates have been synthesised using Ni(II) acetylacetonate as nickel precursor and a succession of ligands derived from phosphinic acid: ethyl-butyl-phosphinic acid, ethyl-butyl-thio-phosphinic acid, and respectively ethylbutyl-di-thio-phosphinic acid. Chemical analysis gel-chromatography, infrared spectroscopy (IR), spin electronic resonance (RES), X-ray diffraction (XRD), thermal gravimetric analysis (TGA), electrical resistance measurements at different temper...
Autori: Daniel Sutiman, Doina Sibiescu, , Mircea Teodor Nechita
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25118

In recent years, the release of volatile organic compounds (VOCs) has received much attention. Catalytic oxidation of VOCs, found in small concentration in industrial gas emissions constitutes an alternative for environmental pollution reduction.In this paper, a comparative study regarding the non-catalytic and catalytic oxidative destruction of non-halogenated or halogenated C6 hydrocarbons (C6H14, C6H12, C6H6, Cl-C6H5, Br-C6H5), is presented. Catalytic oxidation was studied in the presence of ...
Autori: Florin Bandrabur, Heinz Koser, Ion Balasanian, Liliana Lazar
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25162

? Kinetics considerations concerning the oxidative degradation by photo-fenton process of some antibiotics ? Catalytic wet hydrogen peroxide oxidation of 4-chlorophenol over iron-exchanged clays ? Researches on the negative effects assessment (slugging, clogging, ash deposits) developed at the biomass-coal co-firing ? Contribution to the study of the environmental heritage of a former chemical plant ? Impact of chemicals on derivatives with important therapeutic activity in C...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25376

Abstract Wood has been used as an engineering material because it is low in cost, renewable and strong and it requires low processing energy. Wood has many excellent properties that result from its exceptional combination of microstructural, ultrastructural and molecular features. The main drawback is its dimensional instability in the presence of moisture, which can affects also the biological stability. Wood is susceptible to degradation in a number of ways, including rot or decay, insect a...
Autori: Lucia Dumitrescu, Ileana Manciulea
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25473

Abstract In the study, the accumulation of secondary metabolites present in Calendula officinalis L. flowers with importance in therapeutics was examined, after the treatment with some substances considered being mutagens. The effect of substances appliedat different concentrations and different times of action was studied, qualitatively and quantitatively, considering various methanol extracts, obtained from the inflorescenses of Calendula officinalis L, which contained polyphenolic fraction...
Autori: Brindusa Robu, Constantin Leonte, Elvira Gile, Roxana Vatavu, Teodor Robu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25598

Abstract:A method based on headspace and capillary gas chromatography with flame ionization detector technique was validated for thesimultaneous determination of five individual aromatic volatile pollutants: benzene, toluene, ethylbenzene, m/p-xylene and oxylene.The validation took in consideration liniarity, accuracy, precision, limit of detection, limit of quantification anduncertainty estimation criteria and concluded that the proposed method is suitable to determine the pollutants of interes...
Autori: Camelia Draghici, Elena Paunescu, Elisabeta Chirilă, Gabriela Stanciu, Simona Dobrinas
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25729

The aquatic species are permanently subjected to various stresses through the ecosystem and the food habit. Elucidating the impact at the cellular level allows us to understand the ways in which the polluting elements and their derivatives can disrupt the metabolism of aquatic organisms triggering apoptosis in individual cells or necrosis affecting groups of neighbouring cells. The aim of this preliminary study is to highlight the influence of the environmental factors on two fish population by ...
Autori: , Camelia Ureche, Dorel Ureche, Gabriel Lazar, Ileana Denisa Nistor, Irina Loredana Ifrim, Iuliana Mihaela Lazar, Marius Stamate, Valentin Nedeff
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25861

Five new aryloxyalkylcarboxylic acid derivatives (diazoaminoderivatives) are studied for their thermal behavior by applying a coupled TG-FTIR technique over the (30-400 oC) range in correlation with the environmental impact of gaseous species resulting by thermal degradation. These compounds are of a particular practical significance since they show a high biological potential as agrochemicals, such as pesticides (herbicides, acaricides, fungicides, growing stimulators etc.). This is why the pap...
Autori: Anca Mihaela Mocanu, Carmen Zaharia, Constantin Iordache, Constantin Luca, Lucia Odochian
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25899

AbstractEight species of macromycetes which grow in phytocoenosis from “Călimani National Park” (Eastern Carpathians, Romania)have been analysed using Fourier Transform Infrared spectroscopy (FTIR). Among the analysed species, five species are beingconsidered edible (Clitopilus prunulus, Pleurotus eryngii, Macrolepiota rhacodes, Lacaria laccata and Suillus luteus) and threespecies are being considered toxic (Lyophyllum connatum, Paxillus involutus şi Gyromitra infula). The results of f...
Autori: Aurel Pui
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26091

The book edited by Haibo Xie and NicholasGathergood focuses on one of the most importantscientific issues of the 21 century which is thereplacing fossil fuel with sustainable alternatives suchas biomass. Fossil fuels are conventional rawmaterials for many industrial sectors includingchemical and energy production. Usage of fossil fuelis limited by their availability, price and carbonfootprint. Biomass is a renewable resource globallyavailable, cheaper and carbon sequestering. Step bystep shiftin...
Autori: Adrian Catalin Puitel
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26101

Abstract Dipyridine derivatives are used on large scale and pose significant environmental problems. We have synthesized dipyridine derivatives with: 5-chlorovaleric acid, α-dichlorhidrin, iodoacetamide and 11-bromoundecanoic acid. The synthesized substituted compounds were investigated by LC-MS. The adsorptive removal of dipyridine derivatives from aqueous solution has been studied using medicinal activated carbon. The adsorption rate has been investigated under the controlled process...
Autori: Ana Chira
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26638

Abstract Temperature-dependent d.c. electric conductivity of some recently synthesized organic compounds, 4,7-phenanthroline derivatives is studied. Thin-film samples (d=0.34-0.63 m) spin-coated from dimethylformamide solutions onto glass substrates have been used. Organic films with reproducible electron transport properties can be obtained if, after deposition, they are submitted to a heat treatment within temperature range of 298523K. Examined organic compounds in thin fil...
Autori: Cristina M. Al Matarneh
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26656

Abstract In the present paper we studied the competitive transport of p-nitrophenol (pNP) and 2,4-dinitrophenol (2,4-dNP) from aqueous media using the technique of liquid membranes. This technique is very efficient, economic and selective when compared to other removal techniques of phenolic derivatives. The paper presents the influence of the sodium carbonate concentration from the stripping phase, the influence of the concentration ratio [2,4-dNP]/[pNP] upon the selectivity of the transpor...
Autori: Ioana Diaconu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26681

Abstract The present study explores the potential of Streptococcus epidermis, an indigenous isolate for biotransformation of phenol and phenol derivatives. Different phenolic derivatives such as 4-methylphenol, methylbenzene, 2,4-dichlorophenol, 2,6- dichlorophenol and 4-nitrophenol were attempted for biotransformation study. The results have shown that 4-nitrophenol was best transformed. The effect of degradation parameters like pH and temperature was studied, showing the value of 7.0 as o...
Autori: Bhavana V. Mohite
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26705

Abstract The goal of this paper is to investigate the decomposition of aqueous solutions of Azorubin (E122), i.e., an azo dye used in food industry, in a pulsed gliding arc discharge reactor (direct treatment). Air and Argon as carrier gases with solution spray has been considered, as a first approach. The bleaching of the aqueous solution was observed immediately after direct plasma treatment and the decreasing of the dye concentration have been emphasized. Further more, the dye concentrati...
Autori: Marius Ursache
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26898

Renewable resources, biopolymers and bio-based materials are keywords of the sustainable development and environmental sustainability concepts. Biopolymers, the green alternatives to fossil fuel based polymers, have already found different feasible applications, from consumer goods to regenerative medicine. Keratin is the biopolymer contained in the skin derivatives and appendages and is one of the the proteins with the most sophisticated architecture nature could produce. It is found in huge...
Autori: Hossein Rajabinejad
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27043

It is acknowledged that organic fertilizers and wastes, such as animal slurries/manure from intensive farm enterprise, sewage sludge, poultry litter are and will continue to be spread on agricultural land and provide beneficial nutrients to crops. However, many of these materials which are also potentially polluting if not properly managed can pose a risk to groundwater and surface water quality. Generally, their distribution on the soil is performed with specialized machines to reduce the risk...
Autori: Vasilica Ştefan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27545

In this study, the concentrations of 15 phenol derivatives were analyzed from the phreatic and groundwater wells surrounding a decommissioned chemical factory in a village from the western part of Romania. An UPLC-MS method was used to assess the concentrations of the chemical target compounds in the water samples. The most frequent compounds were 4-chlorophenol, 4-tertoctylphenol and 4-nonylphenol, being detected in 17 of the 19 sampling sites, while the least frequent compound was 2,4,6- t...
Autori: Elena Preda
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27661

The synthesis of dimethylamino-propylamine pullulan, DMAPA-P, with a substitution degree of 0.4 was performed in dimethylsulfoxide using N,N’-carbonyldiimidazole as activator and dimethylaminopropylamine as amination agent. Then, two quaternary derivatives (trimethylammonium-propylamine pullulan, TMAPA-P, and benzyldimethylammonium-propylamine pullulan, BzDMAPA-P) were prepared from DMAPA-P by quaternization with methyl iodide and benzyl chloride. The behavior of new pullulan derivativ...
Autori: Anca Giorgiana Grigoras
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27902

Since the middle of the past century, when the synthetic fibers began their rise, wool has steadily lost importance in the textile sector, and now is a marginal fiber on the textiles market. Great amounts of non-marketed raw wool have turned from an income source for sheep farmers into a problematic waste, which is, at best, burn or landfill. With increasing interest for sustainable use of natural resources, wool was reconsider as an underrated, underused renewable resource, worthy of a bette...
Autori: Hossein Rajabinejad
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28031

The goal of this paper is to contribute to environmental improvement. This goal has been achieved by the development of an algorithm that allows the optimization of fuel consumption and transport of combustion products. The paper considers the outlier – robust recursive algorithm. This algorithm is used for identification of multivariable ARMAX (Autoregressive Moving Average with Exogenous Variables) models. In this paper, we introduce pseudo-Huber loss function which is a continuous nonli...
Autori: Vojislav Filipovic
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28167